2-Chloro-N-(2-chloro­benzo­yl)benzene­sulfonamide

نویسندگان

  • P. A. Suchetan
  • B. Thimme Gowda
  • Sabine Foro
  • Hartmut Fuess
چکیده

In the structure of the title compound, C(13)H(9)Cl(2)NO(3)S, the N-H bond is anti to the C=O bond and the dihedral angle between the two aromatic rings is 76.9 (1)°. In the crystal structure, mol-ecules are linked by N-H⋯O(S) hydrogen bonds to form inversion dimers.

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2-Chloro-N-(4-chloro­benzo­yl)benzene­sulfonamide toluene hemisolvate

The unit cell of the title compound, C(13)H(9)Cl(2)NO(3)S·0.5C(7)H(8), contains two mol-ecules of 2-chloro-N-(4-chloro-benzo-yl)benzene-sulfonamide and one toluene mol-ecule, which is disordered about a centre of inversion. The dihedral angle between the two aromatic rings is 85.7 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.

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4-Chloro-N-(3-chloro­benzo­yl)benzene­sulfonamide monohydrate

In the title compound, C(13)H(9)Cl(2)NO(3)S·H(2)O, the conformation of the C=O bond is syn to the meta-Cl group in the benzoyl ring. The mol-ecules are twisted at the S-N bond with a C-S-N-C torsion angle of 72.9 (2)°. The dihedral angle between the sulfonyl benzene ring and the S-NH-C-O segment is 77.8 (1)° and that between the sulfonyl and benzoyl benzene rings is 80.5 (1)°. In the crystal, m...

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010